Abstract
Reduction of the precious metal loading of a catalyst generally causes a decline in light-off performance.Study of the low temperature reaction mechanism of catalysts indicated the importance of the top layer in the reaction, thus increasing reactivity in the top layer was established as an objective. The concentration of precious metals in the top layer was increased, and the thickness of the layers was reduced. At the same time, the preciousmetal loading of the subjacent layer, which contributes little to light-off performance, was reduced by 80%. However, increasing the concentration of precious metals in the top layer caused a reduction in performance due to a sintering effect between the metals. Research was therefore conducted on the employment of a high-thermostability support material (alumina) to control the sintering.This research has enabled the development of a three-way catalyst with significantly reduced precious metal loading while retaining conversion performance equivalent to that of conventional catalysts.
References
- (1) Jidoushahaishutugasu no Keisoku to Sikenhou, Jidousha to Kankyou, Automotive engineering completion, Jidousha Kougaku Zensho Henshuuiinkai, p. 37-54 (1980) (in Japanese)
- (2) Yasui, Y., Ueno, M., Akazaki, S., Iwaki, Y.: Adaptive Sliding Mode Control for Secondary O2 Feedback, A Second Report, HONDA R&D Technical Review, Vol. 11, No. 2, p. 51-56
- (3) Ueno, M., Akazaki, S., Yasui, Y., Iwaki, Y.: A Quick Warmup System during Engine Startup Period Using Adaptive Control of Intake Air And Ignition Timing, HONDA R&D Technical Review, Vol. 11, No. 1, p. 73-78
- (4) JP, 61-46252, A (1986)
- (5) Golden, S. J., Polli, A. D., Hawthorne, R., Hatfield, R., Cotton, M. G., Flynn, K., Truex, T.: Advanced Low PGM Three-Way-Catalyst for LEV-II and ULEV-II Compliance, SAE Paper, 2002-01-0344
- (6) Takaya, M., Yamamoto, S., Ichinose, K., Matsushita, K.: Hydrocardon Trap Technology for the Reduction of Cold-Start Hydrocarbon Emissions, JSAE Annual Congress Proceedings, No. 102 (1998)
- (7) Tanaka, H., Uenishi, M., Tan, I., Kimura, M., Mizuki, J., Nishihata, Y.: An Intelligent Catalyst, SAE Paper, 2001-01-1301
- (8) Yamada, T.: TWC Impact of Revised FTP on Emission and New Modifications Required for Catalysts, SAE Paper, 960793
- (9) Yamada, T.: Development of Zr Containing TWC Catalyst, SAE Paper, 970466
- (10) Kobayash, T.: Improvement of NOx Performance and Thermal Stability in Pd Based Catalyst, SAE Paper, 2000-01-2927
- (11) Omoto, H.: Catalyst Design for Meeting Stringent LEV-2 NOx Regulation, SAE Paper, 2002-01-0348
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Article of Honda R&D Technical Review Vol.17 No.2 (129 - 135)
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Syouji INOSE, Tatsuya OKAYAMA.
Research for High Concentration of Precious Metal and Thin Layer of Catalyst Top Layer
Honda R&D Technical Review Vol.17 No.2 pp.(129 - 135)2005.
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