Abstract
We have developed a new steel strip for gaskets that can seal exhaust gas in 900°C environments. The concept for the material specified the seemingly conflicting requirements of high performance through the active use of γ’-Ni3 (Ti, Al) as a strengthening phase for high-temperature stability, together with a higher melting point for manufacturability. To enhance the relaxation properties, alloying elements that raised the amount and stability of strengthening phase γ’ and suppressed the precipitation of the harmful phase η-Ni3Ti were investigated using thermodynamic calculations, and 5.9 at% of Ti+Al and a ratio of 1.0 of Al/Ti were selected. In addition, to enhance hot rollability, the melting point was increased by reducing Nb and Cr contents as compared to Alloy 718. To maintain initial springiness and the stability of γ’ at high temperatures, the cold rolling reduction ratio was set at 30% to 40%. As a result, in heat load tests at 900°C, gaskets made of the developed alloy performed at the same level as Alloy 718 gaskets at 750°C.
References
- (1) https://www.meti.go.jp/shingikai/sankoshin/sangyo_gijutsu/chikyu_kankyo/pdf/2022_001_03_00.pdf, (2022/5/27)
- (2) Komori, K.: Trend of Exhaust System Material and It’s Future Development, Journal of The Japan Welding Society, Vol. 72, Issue 7, p. 546-551, (2003) (in Japanese)
- (3) Kulawik, K., Buffat, P. A., Kruk, A., Wusatowska-Sarnek, A. M., Czyrska-Filemonowicz, A.: Imaging and characterization of γ’ and γ” nanoparticles in Inconel 718 by EDX elemental mapping and FIB-SEM tomography, Materials Characterization, Vol. 100, p. 74-80, (2015)
- (4) Reed, R. C.: The Superalloys: Fundamentals and Applications, Cambridge University Press, p. 49-51, (2006)
- (5) Reed, R. C.: The Superalloys: Fundamentals and Applications, Cambridge University Press, p. 40-49, (2006)
- (6) Cremisio, R. S., McQueen, H. J.: Some observations of hot working behavior of superalloys according to various types of hot workability tests, Superalloys, G-1-G-36, (1972)
- (7) Sims, C. T., Stoloff, N. S., Hagel, W. C.: Superalloys II: High-Temperature Materials for Aerospace and Industrial Power, Wiley-Interscience, p. 107-109, (1987)
- (8) Fujita, T., Shibata, K.: Nikkeru-ki Chougoukin ni okeru Goukin Genso no Yakuwari, Bulletin of the Japan Institute of Metals, Vol. 16, No. 4, p. 231-239, (1977) (in Japanese)
- (9) Reed, R. C.: The Superalloys: Fundamentals and Applications, Cambridge University Press, p. 238-239, (2006)
- (10) Ueta, S., Noda, T., Okabe, M., Ishida, M., Oketani, H.: Development of Cold-formable Iron-based Superalloy for Exhaust Valves of Motorcycles, DENKI-SEIKO, Vol. 70, No. 3, p. 205-214, (1999) (in Japanese)
- (11) Detrois, M., Jablonski, P. D., Hawk, J. A.: The effect of η phase precipitates on the creep behavior of alloy 263 and variants, Materials Science and Engineering: A, Vol. 799, No. 2, Article 140337, (2021)
- (12) Farvizi, M., Asgari, S.: Effects of cold work prior to aging on microstructure of AEREXTM350 superalloy, Materials Science and Engineering: A, Vol. 480, Issues 1-2, p. 434-438, (2008)
- (13) Katsurai, T., Nishiyama, T., Hamano, S.: Development of High-heat-resistant High-nitrogen Containing Austenitic Stainless Steel for Exhaust Gasket, Honda R&D Technical Review, Vol. 15, No. 2, p. 167-174
- (14) ASTM E328-13: Standard Test Methods for Stress Relaxation for Materials and Structures, (2013)
- (15) Sato, K., Saka, T., Ohno, T., Noda, T.: Development of Low-Nickel Heat-Resistance Alloy for Exhaust Valves, HONDA R&D Technical Review, Vol. 9, p. 185-190, (in Japanese)
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Article of Honda R&D Technical Review Vol.37 (87 - 94)
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Hiroki YAMAMOTO, Isamu SAITO, Yoshiki KUMAGAI, Yoshinori SUMI.
γ’ Precipitation-hardened Cobalt-free Heat-resistant Steel Strip for Exhaust Gaskets Work at 900℃
Honda R&D Technical Review Vol.37 pp.(87 - 94)2025.
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